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Isolation of a 16π‐Electrons 1,4‐Diphosphinine‐1,4‐diide with a Planar C(4)P(2) Ring
Herein, we report the first 1,4‐diphosphinine‐1,4‐diide compound [(ADC(Ph))P](2) (5‐Ph) (ADC(Ph)=PhC{(NDipp)C}(2); Dipp=2,6‐iPr(2)C(6)H(3)) derived from an anionic dicarbene (ADC(Ph)) as a red crystalline solid. Compound 5‐Ph containing a 16π‐electron planar fused‐tricyclic ring system was obtained...
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| Publicado no: | Chemistry |
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| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
John Wiley and Sons Inc.
2021
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7898681/ https://ncbi.nlm.nih.gov/pubmed/33080114 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202003617 |
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