Isolation of a 16π‐Electrons 1,4‐Diphosphinine‐1,4‐diide with a Planar C(4)P(2) Ring

Herein, we report the first 1,4‐diphosphinine‐1,4‐diide compound [(ADC(Ph))P](2) (5‐Ph) (ADC(Ph)=PhC{(NDipp)C}(2); Dipp=2,6‐iPr(2)C(6)H(3)) derived from an anionic dicarbene (ADC(Ph)) as a red crystalline solid. Compound 5‐Ph containing a 16π‐electron planar fused‐tricyclic ring system was obtained...

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Publicado en:Chemistry
Autores principales: Rottschäfer, Dennis, Neumann, Beate, Stammler, Hans‐Georg, Sergeieva, Tetiana, Andrada, Diego M., Ghadwal, Rajendra S.
Formato: Artigo
Lenguaje:Inglês
Publicado: John Wiley and Sons Inc. 2021
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC7898681/
https://ncbi.nlm.nih.gov/pubmed/33080114
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202003617
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