Metalloradical Cations and Dications Based on Divinyldiphosphene and Divinyldiarsene Ligands

Metalloradicals are key species in synthesis, catalysis, and bioinorganic chemistry. Herein, two iron radical cation complexes (3‐E)GaCl(4) [(3‐E)(.+) = [{(IPr)C(Ph)E}(2)Fe(CO)(3)](.+), E = P or As; IPr = C{(NDipp)CH}(2), Dipp = 2,6‐iPr(2)C(6)H(3)] are reported as crystalline solids. Treatment of th...

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Pubblicato in:Chemistry
Autori principali: Sharma, Mahendra K., Rottschäfer, Dennis, Neumann, Beate, Stammler, Hans‐Georg, Danés, Sergi, Andrada, Diego M., van Gastel, Maurice, Hinz, Alexander, Ghadwal, Rajendra S.
Natura: Artigo
Lingua:Inglês
Pubblicazione: John Wiley and Sons Inc. 2021
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Full Papers
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC8048781/
https://ncbi.nlm.nih.gov/pubmed/33470468
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202100213
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