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Photocatalytic carbanion generation from C–H bonds – reductant free Barbier/Grignard-type reactions
We report a redox-neutral method for the generation of carbanions from benzylic C–H bonds in a photocatalytic Grignard-type reaction. The combination of photo- and hydrogen atom transfer (HAT) catalysis enables the abstraction of a benzylic hydrogen atom, generating a radical intermediate. This radi...
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| Pubblicato in: | Chem Sci |
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| Autori principali: | , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
The Royal Society of Chemistry
2019
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8133029/ https://ncbi.nlm.nih.gov/pubmed/34040714 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc04987h |
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