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Total synthesis of (–)-4-desacetoxy-1-oxovindoline: Single atom exchange of an embedded core heteroatom in vindoline
A concise total synthesis of (–)-4-desacetoxy-1-oxovindoline is disclosed, bearing a single heteroatom exchange in the core structure of the natural product 4-desacetoxyvindoline. Central to the synthesis is powerful oxadiazole intramolecular [4+2]/[3+2] cycloaddition cascade that formed four C–C bo...
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| Udgivet i: | Tetrahedron |
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| Main Authors: | , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2021
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8117404/ https://ncbi.nlm.nih.gov/pubmed/33994597 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2021.132117 |
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