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Ascorbate Peroxidase Compound II Is an Iron(IV) Oxo Species

The protonation state of the iron(IV) oxo (or ferryl) form of ascorbate peroxidase compound II (APX-II) is a subject of debate. It has been reported that this intermediate is best described as an iron(IV) hydroxide species. Neutron diffraction data obtained from putative APX-II crystals indicate a p...

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Détails bibliographiques
Publié dans:J Am Chem Soc
Auteurs principaux: Ledray, Aaron P., Krest, Courtney M., Yosca, Timothy H., Mittra, Kaustuv, Green, Michael T.
Format: Artigo
Langue:Inglês
Publié: 2020
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC8107191/
https://ncbi.nlm.nih.gov/pubmed/33170000
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c09108
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