Triggering the Generation of an Iron(IV)-Oxo Compound and Its Reactivity toward Sulfides by Ru(II) Photocatalysis

[Image: see text] The preparation of [Fe(IV)(O)(MePy(2)tacn)](2+) (2, MePy(2)tacn = N-methyl-N,N-bis(2-picolyl)-1,4,7-triazacyclononane) by reaction of [Fe(II)(MePy(2)tacn)(solvent)](2+) (1) and PhIO in CH(3)CN and its full characterization are described. This compound can also be prepared photochem...

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Autores principales: Company, Anna, Sabenya, Gerard, González-Béjar, María, Gómez, Laura, Clémancey, Martin, Blondin, Geneviève, Jasniewski, Andrew J., Puri, Mayank, Browne, Wesley R., Latour, Jean-Marc, Que, Lawrence, Costas, Miquel, Pérez-Prieto, Julia, Lloret-Fillol, Julio
Formato: Artigo
Lenguaje:Inglês
Publicado: American Chemical Society 2014
Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC3985778/
https://ncbi.nlm.nih.gov/pubmed/24568126
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja412059c
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