Octahedral iron(iv)–tosylimido complexes exhibiting single electron-oxidation reactivity

High valent iron species are very reactive molecules involved in oxidation reactions of relevance to biology and chemical synthesis. Herein we describe iron(iv)–tosylimido complexes [Fe(IV)(NTs)(MePy(2)tacn)](OTf)(2) (1((IV))[double bond, length as m-dash]NTs) and [Fe(IV)(NTs)(Me(2)(CHPy(2))tacn)](O...

Popoln opis

Shranjeno v:
Bibliografske podrobnosti
izdano v:Chem Sci
Main Authors: Sabenya, Gerard, Gamba, Ilaria, Gómez, Laura, Clémancey, Martin, Frisch, Jonathan R., Klinker, Eric J., Blondin, Geneviève, Torelli, Stéphane, Que, Lawrence, Martin-Diaconescu, Vlad, Latour, Jean-Marc, Lloret-Fillol, Julio, Costas, Miquel
Format: Artigo
Jezik:Inglês
Izdano: Royal Society of Chemistry 2019
Teme:
Chemistry
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC6979323/
https://ncbi.nlm.nih.gov/pubmed/32055323
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc02526j
Oznake: Označite
Brez oznak, prvi označite!

Podobne knjige/članki