Octahedral iron(iv)–tosylimido complexes exhibiting single electron-oxidation reactivity

High valent iron species are very reactive molecules involved in oxidation reactions of relevance to biology and chemical synthesis. Herein we describe iron(iv)–tosylimido complexes [Fe(IV)(NTs)(MePy(2)tacn)](OTf)(2) (1((IV))[double bond, length as m-dash]NTs) and [Fe(IV)(NTs)(Me(2)(CHPy(2))tacn)](O...

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Publicado en:Chem Sci
Autores principales: Sabenya, Gerard, Gamba, Ilaria, Gómez, Laura, Clémancey, Martin, Frisch, Jonathan R., Klinker, Eric J., Blondin, Geneviève, Torelli, Stéphane, Que, Lawrence, Martin-Diaconescu, Vlad, Latour, Jean-Marc, Lloret-Fillol, Julio, Costas, Miquel
Formato: Artigo
Lenguaje:Inglês
Publicado: Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC6979323/
https://ncbi.nlm.nih.gov/pubmed/32055323
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc02526j
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