Selective C–H halogenation over hydroxylation by non-heme iron(iv)-oxo

Non-heme iron based halogenase enzymes promote selective halogenation of the sp(3)-C–H bond through iron(iv)-oxo-halide active species. During halogenation, competitive hydroxylation can be prevented completely in enzymatic systems. However, synthetic iron(iv)-oxo-halide intermediates often result i...

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Veröffentlicht in:Chem Sci
Hauptverfasser: Rana, Sujoy, Biswas, Jyoti Prasad, Sen, Asmita, Clémancey, Martin, Blondin, Geneviève, Latour, Jean-Marc, Rajaraman, Gopalan, Maiti, Debabrata
Format: Artigo
Sprache:Inglês
Veröffentlicht: Royal Society of Chemistry 2018
Schlagworte:
Chemistry
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6194801/
https://ncbi.nlm.nih.gov/pubmed/30429994
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc02053a
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