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Selective C–H halogenation over hydroxylation by non-heme iron(iv)-oxo
Non-heme iron based halogenase enzymes promote selective halogenation of the sp(3)-C–H bond through iron(iv)-oxo-halide active species. During halogenation, competitive hydroxylation can be prevented completely in enzymatic systems. However, synthetic iron(iv)-oxo-halide intermediates often result i...
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| Publicado no: | Chem Sci |
|---|---|
| Main Authors: | , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6194801/ https://ncbi.nlm.nih.gov/pubmed/30429994 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc02053a |
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