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Single metal four-electron reduction by U(ii) and masked “U(ii)” compounds
The redox chemistry of uranium is dominated by single electron transfer reactions while single metal four-electron transfers remain unknown in f-element chemistry. Here we show that the oxo bridged diuranium(iii) complex [K(2.2.2-cryptand)](2)[{((Me(3)Si)(2)N)(3)U}(2)(μ-O)], 1, effects the two-elect...
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| Publicado no: | Chem Sci |
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| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
The Royal Society of Chemistry
2021
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8098655/ https://ncbi.nlm.nih.gov/pubmed/33996013 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d1sc00668a |
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