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Sterically controlled reductive oligomerisations of CO by activated magnesium(i) compounds: deltate vs. ethenediolate formation
An extremely bulky, symmetrical three-coordinate magnesium(i) complex, [{((TCHP)Nacnac)Mg}(2)] ((TCHP)Nacnac = [{(TCHP)NCMe}(2)CH](−), TCHP = 2,4,6-tricyclohexylphenyl) has been prepared and shown to have an extremely long Mg–Mg bond (3.021(1) Å) for such a complex. It was shown not to react with ei...
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| Publicado no: | Chem Sci |
|---|---|
| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
The Royal Society of Chemistry
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8152598/ https://ncbi.nlm.nih.gov/pubmed/34109023 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc00836b |
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