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Acyclic 1,2-dimagnesioethanes/-ethene derived from magnesium(i) compounds: multipurpose reagents for organometallic synthesis

Reactions of three magnesium(i) dimers, [{((Ar)Nacnac)Mg–}(2)] ((Ar)Nacnac = [(ArNCMe)(2)CH](–); Ar = xylyl (Xyl), mesityl (Mes) or 2,6-diethylphenyl (Dep)), with either 1,1-diphenylethylene (DPE), α-methylstyrene (MS), trans-stilbene (TS) or diphenylacetylene (DPA) led to the 1,2-addition of the Mg...

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Publicat a:Chem Sci
Autors principals: Dange, Deepak, Gair, Andrew R., Jones, Dafydd D. L., Juckel, Martin, Aldridge, Simon, Jones, Cameron
Format: Artigo
Idioma:Inglês
Publicat: Royal Society of Chemistry 2019
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC6428033/
https://ncbi.nlm.nih.gov/pubmed/30996903
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc00200f
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