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Preparation and reactions of polyfunctional magnesium and zinc organometallics in organic synthesis

Polyfunctional organometallics of magnesium and zinc are readily prepared from organic halides via a direct metal insertion in the presence of LiCl or a Br/Mg-exchange using iPrMgCl·LiCl (turbo-Grignard) or related reagents. Alternatively, such functionalized organometallics are prepared by metalati...

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Détails bibliographiques
Publié dans:Chem Sci
Auteurs principaux: Kremsmair, Alexander, Harenberg, Johannes H., Schwärzer, Kuno, Hess, Andreas, Knochel, Paul
Format: Artigo
Langue:Inglês
Publié: The Royal Society of Chemistry 2021
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC8098701/
https://ncbi.nlm.nih.gov/pubmed/33995997
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d1sc00685a
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