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Enantioselective Synthesis of N-Alkylamines through β-Amino C–H Functionalization Promoted by Cooperative Actions of B(C(6)F(5))(3) and a Chiral Lewis Acid Co-Catalyst
We disclose a catalytic method for β-C(sp(3))–H functionalization of N-alkylamines for synthesis of enantiomerically enriched β-substituted amines, entities prevalent in pharmaceutical compounds and used to generate different families of chiral catalysts. We demonstrate that a catalyst system compri...
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| 出版年: | J Am Chem Soc |
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| 主要な著者: | , , , , , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2021
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8058014/ https://ncbi.nlm.nih.gov/pubmed/33512998 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c13200 |
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