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Enantioselective Conia-Ene-Type Cyclizations of Alkynyl Ketones through Cooperative Action of B(C(6)F(5))(3), N-Alkylamine and a Zn-Based Catalyst
An efficient and highly enantioselective Conia-ene-type process has been developed. Reactions are catalyzed by a combination of B(C(6)F(5))(3), an N-alkylamine and a BOX–ZnI(2) complex. Specifically, through cooperative action of B(C(6)F(5))(3) and amine, ketones with poorly acidic α-C–H bonds can b...
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| Publicado en: | J Am Chem Soc |
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| Autores principales: | , , |
| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
2019
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6595478/ https://ncbi.nlm.nih.gov/pubmed/30786707 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b13757 |
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