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B(C(6)F(5))(3)-Catalyzed C−H Alkylation of N-Alkylamines Using Silicon Enolates without External Oxidant
An efficient method for the coupling of N-alkylamines with silicon enolates to generate β-amino carbonyl compounds is disclosed. These reactions proceed by activation of α-amino C–H bonds by B(C(6)F(5))(3), which likely generates a “frustrated” acid/base complex in the presence of large N-alkylamine...
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| Publicado no: | Org Lett |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6591580/ https://ncbi.nlm.nih.gov/pubmed/30693779 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.8b03959 |
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