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Reactions of [Fe(6)C(CO)(14)(S)](2−): Cluster Growth, Redox, Sulfiding
Redox reactions, substitutions, and metalations are reported for the iron carbido sulfide [Fe(6)C(CO)(14)(S)](2−) ([1](2−)). Dianion [1](2−) oxidized to [Fe(6)C(CO)(16)(S)](0) ([2](0)) upon treatment with of [Fe(C(5)H(5))(2)]BF(4) or HBF(4) (H(2) formation) under an atmosphere of CO. Reaction of [2]...
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| Pubblicato in: | Eur J Inorg Chem |
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| Autori principali: | , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2020
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8054992/ https://ncbi.nlm.nih.gov/pubmed/33883972 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ejic.202000736 |
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