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Iron Carbide−Sulfide Carbonyl Clusters
Described is the preparation of the first iron carbide–sulfides. The cluster [Fe(6)C(CO)(15)(SO(2))](2−)([2](2−)), which is generated quantitatively from [Fe(6)C-(CO)(16)](2−) ([1](2−)), was O-methylated to give the sulfinite [2Me](−). Demethoxylation of [2Me](−) with BF(3) gave the face-capped octa...
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| Veröffentlicht in: | Inorg Chem |
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| Hauptverfasser: | , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2019
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6602809/ https://ncbi.nlm.nih.gov/pubmed/31184487 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.9b01231 |
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