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Mild Redox Complementation Enables H(2) Activation by [FeFe]-Hydrogenase Models
Mild oxidants such as [Fe(C(5)Me(5))(2)](+) accelerate the activation of H(2) by [Fe(2)[(SCH(2))(2)NBn](CO)(3)(dppv)(PMe(3))](+) ([1](+)). The reaction is first order in [1](+) and [H(2)] but is independent of the E(1/2) and concentration of the oxidant. The analogous reaction occurs with D(2) and p...
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| Main Authors: | , |
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| Format: | Artigo |
| Language: | Inglês |
| Published: |
2011
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| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3115929/ https://ncbi.nlm.nih.gov/pubmed/21548619 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja201731q |
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