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Combining acid-base, redox and substrate binding functionalities to give a complete model for the [FeFe]-hydrogenase

Some enzymes function by coupling substrate turnover with electron transfer from a redox cofactor such as ferredoxin. In the [FeFe]-hydrogenases, nature’s fastest catalysts for the production and oxidation of H(2), the one-electron redox by a ferredoxin complements the one-electron redox by the diir...

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Detalhes bibliográficos
Main Authors: Camara, James M., Rauchfuss, Thomas B.
Formato: Artigo
Idioma:Inglês
Publicado em: 2011
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3464475/
https://ncbi.nlm.nih.gov/pubmed/22169868
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/nchem.1180
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