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Synthesis and Ambiphilic Reactivity of Metalated Diorgano‐Phosphonite Boranes

Unprecedented metalated phosphonite boranes were prepared from PH‐substituted precursors and silyl amides. Although potassium derivatives were thermally stable and could even be isolated and structurally characterised, lithiated analogues proved to be unstable towards self‐condensation under cleavag...

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Detalhes bibliográficos
Publicado no:Chemistry
Main Authors: Hettich, Thomas D., Rudolf, Richard, Feil, Christoph M., Birchall, Nicholas, Nieger, Martin, Gudat, Dietrich
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2021
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8048877/
https://ncbi.nlm.nih.gov/pubmed/33497004
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202005437
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