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Ambiphilic Al−Cu Bonding
Copper‐alumanyl complexes, [LCu‐Al(SiN(Dipp))], where L=carbene=NHC(iPr) (N,N′‐diisopropyl‐4,5‐dimethyl‐2‐ylidene) and (Me2)CAAC (1‐(2,6‐diisopropylphenyl)‐3,3,5,5‐tetramethyl‐pyrrolidin‐2‐ylidene) and featuring unsupported Al−Cu bonds, have been prepared. Divergent reactivity observed with carbodii...
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| Gepubliceerd in: | Angew Chem Int Ed Engl |
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| Hoofdauteurs: | , , , , , |
| Formaat: | Artigo |
| Taal: | Inglês |
| Gepubliceerd in: |
John Wiley and Sons Inc.
2021
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| Onderwerpen: | |
| Online toegang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8252794/ https://ncbi.nlm.nih.gov/pubmed/33899319 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202104658 |
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