Ambiphilic Al−Cu Bonding

Copper‐alumanyl complexes, [LCu‐Al(SiN(Dipp))], where L=carbene=NHC(iPr) (N,N′‐diisopropyl‐4,5‐dimethyl‐2‐ylidene) and (Me2)CAAC (1‐(2,6‐diisopropylphenyl)‐3,3,5,5‐tetramethyl‐pyrrolidin‐2‐ylidene) and featuring unsupported Al−Cu bonds, have been prepared. Divergent reactivity observed with carbodii...

Disgrifiad llawn

Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Cyhoeddwyd yn:Angew Chem Int Ed Engl
Prif Awduron: Liu, Han‐Ying, Schwamm, Ryan J., Hill, Michael S., Mahon, Mary F., McMullin, Claire L., Rajabi, Nasir A.
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: John Wiley and Sons Inc. 2021
Pynciau:
Communications
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC8252794/
https://ncbi.nlm.nih.gov/pubmed/33899319
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202104658
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