Synthesis and Ambiphilic Reactivity of Metalated Diorgano‐Phosphonite Boranes

Unprecedented metalated phosphonite boranes were prepared from PH‐substituted precursors and silyl amides. Although potassium derivatives were thermally stable and could even be isolated and structurally characterised, lithiated analogues proved to be unstable towards self‐condensation under cleavag...

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Опубликовано в: :Chemistry
Главные авторы: Hettich, Thomas D., Rudolf, Richard, Feil, Christoph M., Birchall, Nicholas, Nieger, Martin, Gudat, Dietrich
Формат: Artigo
Язык:Inglês
Опубликовано: John Wiley and Sons Inc. 2021
Предметы:
Communications
Online-ссылка:https://ncbi.nlm.nih.gov/pmc/articles/PMC8048877/
https://ncbi.nlm.nih.gov/pubmed/33497004
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202005437
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