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SmI(2)-Catalyzed Intermolecular Coupling of Cyclopropyl Ketones and Alkynes: A Link between Ketone Conformation and Reactivity

[Image: see text] The archetypal single electron transfer reductant, samarium(II) diiodide (SmI(2), Kagan’s reagent), remains one of the most important reducing agents and mediators of radical chemistry after four decades of widespread use in synthesis. While the chemistry of SmI(2) is very often un...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Agasti, Soumitra, Beattie, Nicholas A., McDouall, Joseph J. W., Procter, David J.
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2021
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8028054/
https://ncbi.nlm.nih.gov/pubmed/33629852
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.1c01356
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