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Copper‐Catalyzed Borylative Cross‐Coupling of Allenes and Imines: Selective Three‐Component Assembly of Branched Homoallyl Amines

A copper‐catalyzed three‐component coupling of allenes, bis(pinacolato)diboron, and imines allows regio‐, chemo‐, and diastereoselective assembly of branched α,β‐substituted‐γ‐boryl homoallylic amines, that is, products bearing versatile amino, alkenyl, and borane functionality. Alternatively, conve...

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Bibliografiske detaljer
Udgivet i:Angew Chem Int Ed Engl
Main Authors: Rae, James, Yeung, Kay, McDouall, Joseph J. W., Procter, David J.
Format: Artigo
Sprog:Inglês
Udgivet: John Wiley and Sons Inc. 2015
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4736445/
https://ncbi.nlm.nih.gov/pubmed/26632675
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201508959
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