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Enantio‐ and Diastereoselective Synthesis of Homopropargyl Amines by Copper‐Catalyzed Coupling of Imines, 1,3‐Enynes, and Diborons

An efficient, enantio‐ and diastereoselective, copper‐catalyzed coupling of imines, 1,3‐enynes, and diborons is reported. The process shows broad substrate scope and delivers complex, chiral homopropargyl amines; useful building blocks on the way to biologically‐relevant compounds. In particular, fu...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Manna, Srimanta, Dherbassy, Quentin, Perry, Gregory J. P., Procter, David J.
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7383811/
https://ncbi.nlm.nih.gov/pubmed/31917893
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201915191
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