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Enantio‐ and Diastereoselective Synthesis of Homopropargyl Amines by Copper‐Catalyzed Coupling of Imines, 1,3‐Enynes, and Diborons

An efficient, enantio‐ and diastereoselective, copper‐catalyzed coupling of imines, 1,3‐enynes, and diborons is reported. The process shows broad substrate scope and delivers complex, chiral homopropargyl amines; useful building blocks on the way to biologically‐relevant compounds. In particular, fu...

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Pubblicato in:Angew Chem Int Ed Engl
Autori principali: Manna, Srimanta, Dherbassy, Quentin, Perry, Gregory J. P., Procter, David J.
Natura: Artigo
Lingua:Inglês
Pubblicazione: John Wiley and Sons Inc. 2020
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC7383811/
https://ncbi.nlm.nih.gov/pubmed/31917893
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201915191
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