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Copper‐Catalyzed Borylative Cross‐Coupling of Allenes and Imines: Selective Three‐Component Assembly of Branched Homoallyl Amines

A copper‐catalyzed three‐component coupling of allenes, bis(pinacolato)diboron, and imines allows regio‐, chemo‐, and diastereoselective assembly of branched α,β‐substituted‐γ‐boryl homoallylic amines, that is, products bearing versatile amino, alkenyl, and borane functionality. Alternatively, conve...

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Dades bibliogràfiques
Publicat a:Angew Chem Int Ed Engl
Autors principals: Rae, James, Yeung, Kay, McDouall, Joseph J. W., Procter, David J.
Format: Artigo
Idioma:Inglês
Publicat: John Wiley and Sons Inc. 2015
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC4736445/
https://ncbi.nlm.nih.gov/pubmed/26632675
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201508959
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