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(19)F- and (18)F-Arene Deoxyfluorination via Organic Photoredox-Catalysed Polarity-Reversed Nucleophilic Aromatic Substitution
Nucleophilic aromatic substitution (S(N)Ar) is routinely used to install (19)F(−) and (18)F(−) in aromatic molecules, but is typically limited to electron-deficient arenes due to kinetic barriers associated with C–F bond formation. Here we demonstrate that a polarity-reversed photoredox-catalysed ar...
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| Publicado no: | Nat Catal |
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| Main Authors: | , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8009013/ https://ncbi.nlm.nih.gov/pubmed/33791591 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41929-020-0495-0 |
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