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Infrared Spectroelectrochemistry of Iron-Nitrosyl Triarylcorroles. Implications for Ligand Noninnocence
[Image: see text] Recent DFT calculations have suggested that iron nitrosyl triarylcorrole complexes have substantial {FeNO}(7)–corrole(•2–) character. With this formulation, reduction of Fe(C)(NO) complexes, where C = triarylcorrole, should be centered on the corrole macrocycle rather than on the {...
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| Gepubliceerd in: | Inorg Chem |
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| Hoofdauteurs: | , , , , |
| Formaat: | Artigo |
| Taal: | Inglês |
| Gepubliceerd in: |
American Chemical Society
2020
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| Online toegang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7997370/ https://ncbi.nlm.nih.gov/pubmed/32053351 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.9b03613 |
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