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Infrared Spectroelectrochemistry of Iron-Nitrosyl Triarylcorroles. Implications for Ligand Noninnocence
[Image: see text] Recent DFT calculations have suggested that iron nitrosyl triarylcorrole complexes have substantial {FeNO}(7)–corrole(•2–) character. With this formulation, reduction of Fe(C)(NO) complexes, where C = triarylcorrole, should be centered on the corrole macrocycle rather than on the {...
Shranjeno v:
| izdano v: | Inorg Chem |
|---|---|
| Main Authors: | , , , , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
American Chemical Society
2020
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| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7997370/ https://ncbi.nlm.nih.gov/pubmed/32053351 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.9b03613 |
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