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Infrared Spectroelectrochemistry of Iron-Nitrosyl Triarylcorroles. Implications for Ligand Noninnocence

[Image: see text] Recent DFT calculations have suggested that iron nitrosyl triarylcorrole complexes have substantial {FeNO}(7)–corrole(•2–) character. With this formulation, reduction of Fe(C)(NO) complexes, where C = triarylcorrole, should be centered on the corrole macrocycle rather than on the {...

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Pubblicato in:Inorg Chem
Autori principali: Rahman, Md. Hafizur, Ryan, Michael D., Vazquez-Lima, Hugo, Alemayehu, Abraham, Ghosh, Abhik
Natura: Artigo
Lingua:Inglês
Pubblicazione: American Chemical Society 2020
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC7997370/
https://ncbi.nlm.nih.gov/pubmed/32053351
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.9b03613
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