Ligand Noninnocence in Iron Corroles: Insights from Optical and X-ray Absorption Spectroscopies and Electrochemical Redox Potentials

Two new series of iron meso-tris(para-X-phenyl)-corrole (TpXPC) complexes, Fe[TpXPC]Ph and Fe[TpXPC]Tol, in which X=CF(3), H, Me, and OMe, and Tol=p-methylphenyl (p-tolyl), have been synthesized, allowing a multitechnique electronic–structural comparison with the corresponding FeCl, FeNO, and Fe(2)(...

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Bibliographic Details
Published in:Chemistry
Main Authors: Ganguly, Sumit, Giles, Logan J., Thomas, Kolle E., Sarangi, Ritimukta, Ghosh, Abhik
Format: Artigo
Language:Inglês
Published: 2017
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Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC5710759/
https://ncbi.nlm.nih.gov/pubmed/28845891
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201702621
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