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X-ray Absorption Spectroscopy as a Probe of Ligand Noninnocence in Metallocorroles: The Case of Copper Corroles
The question of ligand noninnocence in Cu corroles has long been a topic of discussion. Presented herein is a Cu K-edge X-ray absorption spectroscopy (XAS) study, which provides a direct probe of the metal oxidation state, of three Cu corroles, Cu[TPC], Cu[Br(8)TPC], and Cu[(CF(3))(8)TPC] (TPC = mes...
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| Publicado en: | Inorg Chem |
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| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2019
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6644708/ https://ncbi.nlm.nih.gov/pubmed/31046257 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.9b00128 |
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