Unexpected Molecular Structure of a Putative Rhenium‐Dioxo‐Benzocarbaporphyrin Complex. Implications for the Highest Transition Metal Valence in a Porphyrin‐Type Ligand Environment

A combination of quantum chemical calculations and synthetic studies was used to address the possibility of very high (>6) valence states of transition metals in porphyrin‐type complexes. With corrole as a supporting ligand, DFT calculations ruled out Re(VII) and Ir(VII) dioxo complexes as stable...

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Bibliographic Details
Published in:ChemistryOpen
Main Authors: Alemayehu, Abraham B., Vazquez‐Lima, Hugo, Teat, Simon J., Ghosh, Abhik
Format: Artigo
Language:Inglês
Published: John Wiley and Sons Inc. 2019
Subjects:
Communications
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC6804418/
https://ncbi.nlm.nih.gov/pubmed/31649839
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/open.201900271
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