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A Chiral Pentafluorinated Isopropyl Group via Iodine(I)/(III) Catalysis
An I(I)/(III) catalysis strategy to construct an enantioenriched fluorinated isostere of the (i)Pr group is reported. The difluorination of readily accessible α‐CF(3)‐styrenes is enabled by the in situ generation of a chiral ArIF(2) species to forge a stereocentre with the substituents F, CH(2)F and...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
John Wiley and Sons Inc.
2021
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7986799/ https://ncbi.nlm.nih.gov/pubmed/33427355 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202015946 |
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