Fluorocyclisation via I(I)/I(III) catalysis: a concise route to fluorinated oxazolines

Herein, we describe a catalytic fluorooxygenation of readily accessible N-allylcarboxamides via an I(I)/I(III) manifold to generate 2-oxazolines containing a fluoromethyl group. Catalysis is conditional on the oxidation competence of Selectfluor(®), whilst HF serves as both a fluoride source and Brø...

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Detalhes bibliográficos
Publicado no:Beilstein J Org Chem
Main Authors: Scheidt, Felix, Thiehoff, Christian, Yilmaz, Gülay, Meyer, Stephanie, Daniliuc, Constantin G, Kehr, Gerald, Gilmour, Ryan
Formato: Artigo
Idioma:Inglês
Publicado em: Beilstein-Institut 2018
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Full Research Paper
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6009682/
https://ncbi.nlm.nih.gov/pubmed/29977374
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.14.88
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