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Carbodicarbene Bismaalkene Cations: Unravelling the Complexities of Carbene versus Carbone in Heavy Pnictogen Chemistry
We report a combined experimental and theoretical study on the first examples of carbodicarbene (CDC)‐stabilized bismuth complexes, which feature low‐coordinate cationic bismuth centers with C=Bi multiple‐bond character. Monocations [(CDC)Bi(Ph)Cl][SbF(6)] (8) and [(CDC)BiBr(2)(THF)(2)][SbF(6)] (11)...
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| izdano v: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , , , , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
John Wiley and Sons Inc.
2021
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7986408/ https://ncbi.nlm.nih.gov/pubmed/33290596 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202014398 |
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