Carbodicarbene Bismaalkene Cations: Unravelling the Complexities of Carbene versus Carbone in Heavy Pnictogen Chemistry

We report a combined experimental and theoretical study on the first examples of carbodicarbene (CDC)‐stabilized bismuth complexes, which feature low‐coordinate cationic bismuth centers with C=Bi multiple‐bond character. Monocations [(CDC)Bi(Ph)Cl][SbF(6)] (8) and [(CDC)BiBr(2)(THF)(2)][SbF(6)] (11)...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Walley, Jacob E., Warring, Levi S., Wang, Guocang, Dickie, Diane A., Pan, Sudip, Frenking, Gernot, Gilliard, Robert J.
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2021
Assuntos:
Research Articles
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7986408/
https://ncbi.nlm.nih.gov/pubmed/33290596
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202014398
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