Indirect Access to Carbene Adducts of Bismuth- and Antimony-Substituted Phosphaketene and Their Unusual Thermal Transformation to Dipnictines and [(NHC)(2)OCP][OCP]

[Image: see text] The synthesis and thermal redox chemistry of the first antimony (Sb)– and bismuth (Bi)–phosphaketene adducts are described. When diphenylpnictogen chloride [Ph(2)PnCl (Pn = Sb or Bi)] is reacted with sodium 2-phosphaethynolate [Na[OCP]·(dioxane)(x)], tetraphenyldipnictogen (Ph(2)Pn...

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Gepubliceerd in:Inorg Chem
Hoofdauteurs: Walley, Jacob E., Warring, Levi S., Kertész, Erik, Wang, Guocang, Dickie, Diane A., Benkő, Zoltán, Gilliard, Robert J.
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: American Chemical Society 2021
Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC8277130/
https://ncbi.nlm.nih.gov/pubmed/33689349
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.0c03683
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