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An Iron(IV)-oxo Intermediate Initiating L-Arginine Oxidation but not Ethylene Production by the 2-Oxoglutarate-dependent Oxygenase, Ethylene-Forming Enzyme
Ethylene-forming enzyme (EFE) is an ambifunctional iron(II)- and 2-oxoglutarate-dependent (Fe/2OG) oxygenase. In its major (EF) reaction, it converts carbons 1, 2, and 5 of 2OG to CO(2) and carbons 3 and 4 to ethylene, a four-electron oxidation drastically different from the simpler decarboxylation...
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| 出版年: | J Am Chem Soc |
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| 主要な著者: | , , , , , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2021
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7962147/ https://ncbi.nlm.nih.gov/pubmed/33522811 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c10923 |
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