An Iron(IV)-oxo Intermediate Initiating L-Arginine Oxidation but not Ethylene Production by the 2-Oxoglutarate-dependent Oxygenase, Ethylene-Forming Enzyme

Ethylene-forming enzyme (EFE) is an ambifunctional iron(II)- and 2-oxoglutarate-dependent (Fe/2OG) oxygenase. In its major (EF) reaction, it converts carbons 1, 2, and 5 of 2OG to CO(2) and carbons 3 and 4 to ethylene, a four-electron oxidation drastically different from the simpler decarboxylation...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Copeland, Rachelle A., Davis, Katherine M., Shoda, Tokufu Kent C., Blaesi, Elizabeth J., Boal, Amie K., Krebs, Carsten, Bollinger, J. Martin
Formato: Artigo
Idioma:Inglês
Publicado em: 2021
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7962147/
https://ncbi.nlm.nih.gov/pubmed/33522811
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c10923
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