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Catalytic Asymmetric and Stereodivergent Oligonucleotide Synthesis
We report the catalytic stereocontrolled synthesis of dinucleotides. Chiral phosphoric acid (CPA) catalysts are demonstrated to control the formation of stereogenic phosphorous centers during phosphoramidite transfer for the first time. Unprecedented levels of diastereodivergence are also demonstrat...
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| Publicado en: | Science |
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| Autores principales: | , , , , , |
| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
2021
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7961808/ https://ncbi.nlm.nih.gov/pubmed/33574208 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1126/science.abf4359 |
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