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Catalytic Asymmetric Allylboration of Indoles and Dihydroisoquinolines with Allylboronic Acids: Stereodivergent Synthesis of up to Three Contiguous Stereocenters
The catalytic asymmetric allylboration of cyclic imines with γ,γ‐disubstituted allylboronic acids provides products with adjacent stereocenters in high yield and stereoselectivity. Various electrophiles, including 3,4‐dihydroisoquinolines and indoles, were prenylated in a fully stereodivergent fashi...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
John Wiley and Sons Inc.
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5129484/ https://ncbi.nlm.nih.gov/pubmed/27735124 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201608605 |
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