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Stereodivergent synthesis of vicinal quaternary-quaternary stereocenters and bioactive hyperolactones

Although great success has been achieved in asymmetric Claisen rearrangement for the synthesis of chiral γ,δ-unsaturated carbonyl compounds bearing vicinal tertiary-quaternary stereocenters, the development of asymmetric versions for stereodivergent construction of adjacent quaternary-quaternary ste...

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Detalhes bibliográficos
Publicado no:Nat Commun
Main Authors: Zheng, Haifeng, Wang, Yan, Xu, Chaoran, Xu, Xi, Lin, Lili, Liu, Xiaohua, Feng, Xiaoming
Formato: Artigo
Idioma:Inglês
Publicado em: Nature Publishing Group UK 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5958103/
https://ncbi.nlm.nih.gov/pubmed/29773786
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-018-04123-w
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