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Organocatalytic Synthesis of α-Trifluoromethyl Allylboronic Acids by Enantioselective 1,2-Borotropic Migration
[Image: see text] Chiral α-substituted allylboronic acids were synthesized by asymmetric homologation of alkenylboronic acids using CF(3)/TMS-diazomethanes in the presence of BINOL catalyst and ethanol. The chiral α-substituted allylboronic acids were reacted with aldehydes or oxidized to alcohols i...
Tallennettuna:
| Julkaisussa: | J Am Chem Soc |
|---|---|
| Päätekijät: | , , , , , |
| Aineistotyyppi: | Artigo |
| Kieli: | Inglês |
| Julkaistu: |
American Chemical
Society
2020
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| Linkit: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7760092/ https://ncbi.nlm.nih.gov/pubmed/33270462 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c09923 |
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