Carregant...
Catalytic Asymmetric Total Synthesis of (−)-Actinophyllic Acid
Described herein is a catalytic asymmetric total synthesis of (−)-actinophyllic acid, with the key step being a chiral phosphine-catalyzed [3 + 2] annulation between an imine and an allenoate to form a pyrroline intermediate in 99% yield and 94% ee. The synthesis also features CuI-catalyzed coupling...
Guardat en:
| Publicat a: | J Am Chem Soc |
|---|---|
| Autors principals: | , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2016
|
| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4920546/ https://ncbi.nlm.nih.gov/pubmed/26910382 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b00567 |
| Etiquetes: |
Afegir etiqueta
Sense etiquetes, Sigues el primer a etiquetar aquest registre!
|