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Catalytic Asymmetric Total Synthesis of (−)-Actinophyllic Acid
Described herein is a catalytic asymmetric total synthesis of (−)-actinophyllic acid, with the key step being a chiral phosphine-catalyzed [3 + 2] annulation between an imine and an allenoate to form a pyrroline intermediate in 99% yield and 94% ee. The synthesis also features CuI-catalyzed coupling...
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| Izdano u: | J Am Chem Soc |
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| Glavni autori: | , , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2016
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| Teme: | |
| Online pristup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4920546/ https://ncbi.nlm.nih.gov/pubmed/26910382 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b00567 |
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