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Mechanistic Origins of Regioselectivity in Cobalt-Catalyzed C(sp(2))–H Borylation of Benzoate Esters and Arylboronate Esters
Synthetic and mechanistic investigations into the C(sp(2))–H borylation of various electronically diverse arenes catalyzed by bis(phosphine)pyridine ((iPr)PNP) cobalt complexes are reported. Borylation of various benzoate esters and arylboronate esters gave remarkably high selectivities for the posi...
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| Publicado no: | Chem |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7945986/ https://ncbi.nlm.nih.gov/pubmed/33718656 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.chempr.2020.11.017 |
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