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Mechanistic Origins of Regioselectivity in Cobalt-Catalyzed C(sp(2))–H Borylation of Benzoate Esters and Arylboronate Esters

Synthetic and mechanistic investigations into the C(sp(2))–H borylation of various electronically diverse arenes catalyzed by bis(phosphine)pyridine ((iPr)PNP) cobalt complexes are reported. Borylation of various benzoate esters and arylboronate esters gave remarkably high selectivities for the posi...

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Gorde:
Xehetasun bibliografikoak
Argitaratua izan da:Chem
Egile Nagusiak: Pabst, Tyler P., Quach, Linda, MacMillan, Kaitlyn T., Chirik, Paul J.
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: 2020
Gaiak:
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC7945986/
https://ncbi.nlm.nih.gov/pubmed/33718656
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.chempr.2020.11.017
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