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Mechanistic Investigation of Oxygen Rebound in a Mononuclear Nonheme Iron Complex
An iron(III) methoxide complex reacts with para-substituted triarylmethyl radicals to give iron(II) and methoxyether products. Second-order rate constants for the radical derivatives were obtained. Hammett and Marcus plots suggest the radical transfer reactions proceed via a concerted process. Calcu...
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| Publicado en: | Inorg Chem |
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| Autores principales: | , , , , , , |
| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
2019
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7909310/ https://ncbi.nlm.nih.gov/pubmed/31313577 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.9b01208 |
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