Mechanistic Investigation of Oxygen Rebound in a Mononuclear Nonheme Iron Complex

An iron(III) methoxide complex reacts with para-substituted triarylmethyl radicals to give iron(II) and methoxyether products. Second-order rate constants for the radical derivatives were obtained. Hammett and Marcus plots suggest the radical transfer reactions proceed via a concerted process. Calcu...

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Veröffentlicht in:Inorg Chem
Hauptverfasser: Pangia, Thomas M., Yadav, Vishal, Gérard, Emilie F., Lin, Yen-Ting, de Visser, Sam P., Jameson, Guy N. L., Goldberg, David P.
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2019
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Article
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC7909310/
https://ncbi.nlm.nih.gov/pubmed/31313577
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.9b01208
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