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A (13)C-labeled triarylmethyl radical as EPR spin probe highly sensitive to molecular tumbling

A stable triarylmethyl spin probe whose Electron Paramagnetic Resonance (EPR) spectrum is highly sensitive to molecular tumbling is reported. The strong anisotropy of the hyperfine coupling tensor with the central carbon of a (13)C(1)-labeled triarylmethyl radical enables the measurement of the prob...

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Argitaratua izan da:Angew Chem Int Ed Engl
Egile Nagusiak: Poncelet, Martin, Driesschaert, Benoit
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: 2020
Gaiak:
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC7901239/
https://ncbi.nlm.nih.gov/pubmed/32542924
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202006591
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